Not entirely. Sam was tempted, and if he possessed the ring long enough he would have been overcome like any other, but his Hobbit-sense saved him in that one small moment:
"“As he stood there, even though the Ring was not on him but hanging by its chain about his neck, he felt himself enlarged, as if he were robed in a huge distorted shadow of himself, and vast and ominous threat halted upon the walls of Mordor…”
"Wild fantasies arose in his mind; and he saw Samwise the Strong, Hero of the Age, striding with a flaming sword across the darkened land, and armies flocking to his call as he marched to the overthrow of Barad-dur… He had only to put on the Ring and claim it for his own, and all this could be. "
"In that hour of trial it was the love of his master that helped most to hold him firm; but also deep down in him lived still unconquered his plain hobbit-sense: he knew in the core of his heart that he was not large enough to bear such a burden, even if such visions were not a mere cheat to betray him. The one small garden of a free gardener was all his need and due, not a garden swollen to a realm; his own hands to use, not the hands of others to command. "