@weekend_editor@mathstodon.xyz
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weekend_editor

@weekend_editor@mathstodon.xyz

Retired physicist, after a career in machine learning & stats mostly for cancer drug discovery. Now blogging about stats in the news.

Avatar: convergence basins in the complex plane of Newton's algorithm searching for the cube roots of unity. (After a NYT column by https://mathstodon.xyz/@stevenstrogatz, long ago.)

Header: Quote from GK Chesterton, London Daily News, 1905-Aug-16 on epistemic humility and the ability to say "I am wrong" as the foundation of idealism.

#statistics #physics #r

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pauldrye, to random
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So this happened. Given the colour and the fact they were working with nitric acid, I'm feeling somewhat doubtful this was (relatively benign) nitrous oxide.

Source: https://www.bbc.com/news/articles/cd11xzjkvk0o

weekend_editor,
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@cstross @mmby @nyrath @pauldrye

It sure LOOKS like a cloud of NO2 -- at sufficiently high temperature, it has that red/orange color. No fun to breathe, as it makes nitric acid from water in lung tissue.

A fertilizer plant would plausibly be working with ammonia, which can produce NO2 by the Ostwald process (used for making nitric acid, and this apparently was a plant that did that):

4 NH3 + 7 O2 -> 4 NO2 + 6 H2O

Or a fertilizer plant might also have nitric acid around, and some knucklehead didn't understand to keep it away from copper fittings:

4 HNO3 + Cu -> Cu(NO3)2 + 2 NO2 + 2 H2O

Those are the ones that come to mind as bulk reactions likely to be in a fertilizer plant. There are others, but then you have to figure out why a fertilizer plant might be doing that.

But the spokesperson who said it was "nitrous oxide" (which is transparent) or the reporter who mis-heard it need to have a word with some industrial chemists.

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