Yes. The people who look at your face will notice it consciously if they care about those things, or subconsciously if they don’t (i.e., it will still leave a good impression).
Serum is viscous, almost milky. Toner is watery. Typical rule is for me: cleansing routine (I use a scrub then a foaming cleanser), followed by toner for hydration and exfoliation, followed by serum for spot treatment, followed by moisturizer.
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