I do have this issue occasionally. Here are a few tips:
make sure the metal contacts on the card are facing up (it may feel as if you're putting the card in upside-down)
don't force it
play with the angle a bit; I do find that these microSD card slots can be sensitive to the angle at which the card is being inserted
if all else fails, try removing the back cover of the device; this gives you a bit more room to play with, it can also release some tension (the other day, I couldn't get an SD card out of a device; when I removed the back, the card popped right out)
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