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in 1897.

J. J. Thomson of the Cavendish Laboratory announces his discovery of the electron as a subatomic particle, over 1,800 times smaller than a proton (in the atomic nucleus), at a lecture at the Royal Institution in London.

Thomson showed that cathode rays were composed of previously unknown negatively charged particles (now called electrons), which he calculated must have bodies much smaller than atoms and a very large charge-to-mass ratio.

https://www.gutenberg.org/ebooks/author/38322

The cathode ray tube by which J. J. Thomson demonstrated that cathode rays could be deflected by a magnetic field, and that their negative charge was not a separate phenomenon JJ Thomson - Philosophical Magazine, 44, 293 (1897)

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