moira,
@moira@mastodon.murkworks.net avatar

One year ago I put three test objects, two PLA, one PHA, outside in a flower pot half-buried. I just brought them inside. Let’s see what happened!

jeroen,
@jeroen@sociabl.be avatar

@moira
It's very cool to read. Thanks for your patience and sharing.
I have a PLA printed Honda logo that's been hanging on my motorcycle for 6 years and still looks brand new. I expected more degradation. @bart

jigmedatse,
@jigmedatse@social.jigmedatse.com avatar

@moira They turned into moss?

moira,
@moira@mastodon.murkworks.net avatar
jigmedatse,
@jigmedatse@social.jigmedatse.com avatar

@moira Just enjoying the moss you have growing there. Sorry to have confused...

tristan,
@tristan@mastodon.au avatar

@moira I'm curious where this test was done and how severe the weather (UV/temp/direct sun/ECT) was. Where I live, I made some pla planter signs for the garden and they didn't last one summer. The PETG ones I made are going on their 4th with no signs of deterioration other than one that got broken

moira,
@moira@mastodon.murkworks.net avatar

@tristan North of Seattle, full sun exposure half the day (and in summer we have like 18 hour days at peak), you can check our historical temperatures and weather for the whole year I think at places like ambientweather and weatherunderground if you like.

moira,
@moira@mastodon.murkworks.net avatar

@tristan but mostly we don't get the UV hammer you do places like Hawai'i because the sun is mostly at a lower to much lower angle than with places further south. Goes through a lot more atmosphere.

tristan,
@tristan@mastodon.au avatar

@moira haha yeah just looked it up and the highest there is less than half our average (regional Australia). That would make a huge difference

moira,
@moira@mastodon.murkworks.net avatar

We had a freeze last night too. Soil is very wet and cold even after being in sun earlier today.

moira,
@moira@mastodon.murkworks.net avatar

White seems largely unaffected. The shape distortion is from the previous glass point testing.

Same white rectangle cleaned up a bit. The dirt side is very slightly darker, which is the most visible effect.

moira,
@moira@mastodon.murkworks.net avatar

It was not a hot summer, which arguably was a bit disappointing from this test standpoint. Regardless, the PLA held up fine, as expected. I’ve seen oil-plastics do much worse - including the flowerpot I used which faded quite a bit!

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira This is a cool experiment.

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman thanks! i had leftover parts from another experiment so thought to use them for this ^_^

moira,
@moira@mastodon.murkworks.net avatar

The 20% wood infill is much more strongly affected, though I think more by the sun than being buried! Lots of fading and feels a little brittle.

The object cleaned. Areas exposed to sun are much lighter. The object was labelled PLA Wood 20% and the sharpie ink also faded in the sun-exposed areas.

moira,
@moira@mastodon.murkworks.net avatar

Yeah the sun exposed part is definitely weaker.

moira,
@moira@mastodon.murkworks.net avatar

oooh the did something weird! Look at that layer compression in a year of full exposure!

PLA stacked against PHA; the PLA layer heights remained stable, the PHA compressed in the sun, but only along the Z axis

moira,
@moira@mastodon.murkworks.net avatar

The feels weaker on the sun-exposed side too, but not brittle.

moira,
@moira@mastodon.murkworks.net avatar

oh dang look - is showing some self-composting breakdown as it dries!

this is more along the lines of my expectations; and PHA do both biodegrade but PHA is (reportedly) better at it. I think we’re seeing that here, particularly since it’s mostly in the buried portion!

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira I wonder what happens if you put PLA in a reactant. Does baking soda react with it over time?

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman I don’t know!

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman Mostly what I was wondering about was how much more quickly PHA would degrade than PLA in a full-exposure environment where I live. Given that both PHA and PLA get their carbon from plants, which in turn get it from the air, via carbon-dioxide extraction, I’m not actually interested in trying to break either down more quickly - as medium-term carbon stores, I think we should be thinking about how to break them down less quickly and maybe stacking up bricks of it in abandoned coal mines or something.

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira I doubt the carbon cost of making such bricks is worth it. But you can turn CO2 into carbon fiber.

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman Well, that's the trick, isn't it? Figuring out carbon-neutral ways to produce stuff in general, then applying that to PLA, then storing it in a way that makes it take a very, very long time to break down. Making very-low-density coal, effectively.

I'm not saying I KNOW THE WAY!! or something, it's just a thought I toy with. It - or more likely something higher density, see also your carbon fibres, and in some fiction I've written literally artificially-produced diamond sheets - is probably one of the many ways we'll have to use to get out of this mess.

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman The difference being, of course, that we already have a lot of infrastructure around making plastic. We don't have that for diamond, coal, and so forth.

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira And plastic remains an amazing material. Its degradation over time into "useless plastic" without becoming "dirt" is really a problem though.

Diamond takes a lot of energy (heat and pressure), which probably has a positive carbon footprint. If you can do it with solar, it's another matter.

But getting old plastic back to being good plastic seems to be the challenge. As always, it's a matter of pushing the molecules uphill. That energy has to come from somewhere.

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira I just looked to make sure: PLA’s degradation releases CO2, which is too bad. I was hoping it was something that could become plant-accessible.

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman All composting releases CO2. What you work to try to do is skip the methane step before the methane also breaks down to CO2.

And CO2 in the air is plant-accessible; that's where they get their carbon.

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira Sorry, I meant, I was hoping there was a way to make it carbonaceous soil.

I wonder if there’s a “bacteria to CO2 to plant” symbiont that could be cultivated. A purpose-built lichen.

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman Oh okay yeah that makes more sense. And yeah definitely not, which I suppose is too bad.

PLA is an acceptable material to me but I’m really hanging a lot of hopes on PHA and variants.

I should redo this test with a pure PHA without wood infill.

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira I'm excited to see the results!

moira,
@moira@mastodon.murkworks.net avatar

@JoshuaACNewman Well you’ll be waiting a while xD

JoshuaACNewman,
@JoshuaACNewman@xeno.glyphpress.com avatar

@moira The hottest October in recorded history should help!

moira,
@moira@mastodon.murkworks.net avatar

It’s interesting that the shows very little bleaching in the sun exposed portion but much more so from underground, the opposite of the , despite the layer compression. Neat!

moira,
@moira@mastodon.murkworks.net avatar

Oh wow I forgot! Here’s the bit of softwood I put into the dirt at the same time! It seems almost as unaffected as the white PLA. No really, it’s taking longer to dry but otherwise it feels the same on both ends.

moira,
@moira@mastodon.murkworks.net avatar

The wood control really shows very little decomposition so do not mistake this for a composting experiment, it’s more of an outdoor durability experiment.

moira,
@moira@mastodon.murkworks.net avatar

Anyway, that’s it for the sample retrieval (unboxing? lol) so I hope you enjoyed it. Don’t forget to like and oh wait this isn’t youtube lol xD

Bye! xD

alltherum,
@alltherum@freeradical.zone avatar

@moira Do you know the soil pH? I'm surprised the wood didn't degrade more.

moira,
@moira@mastodon.murkworks.net avatar

@alltherum It’s ordinary general-purpose potting soil from a bag of potting soil. Wait, I still have more which means I still have the bag!

It’s this!

ingredients list and full composition breakdown from the back of the bag

alltherum,
@alltherum@freeradical.zone avatar

@moira Interesting! That should have ideal pH levels, which makes me wonder if they sterilize the soil before bagging it.

moira,
@moira@mastodon.murkworks.net avatar

@alltherum I kinda suspect so. I mean, I did keep stuff out of the pot, but we still got very little moss.

linux_mclinuxface,
@linux_mclinuxface@fosstodon.org avatar

@moira neat experiment!

A flower pot can tell us a lot but isn’t a perfect setting. A real compost heap that got up to temperature would be a very interesting comparison. Also just in-ground with soil critters.

moira,
@moira@mastodon.murkworks.net avatar

@linux_mclinuxface But as I said: this wasn't about composting. This was about exposure durability to weather.

linux_mclinuxface,
@linux_mclinuxface@fosstodon.org avatar

@moira ah, I get it!

So PHA is not great for weather.

I wonder how it does in extreme cold. I know PLA behaves very strangely at -35c.

moira,
@moira@mastodon.murkworks.net avatar

@linux_mclinuxface PHA is definitely not good for soil contact or a year exposed to direct sunlight. (At a point that's about as sunny as our location gets anyway.)

linux_mclinuxface,
@linux_mclinuxface@fosstodon.org avatar

@moira my go-to for outdoor use is TPU or PETG.

moira,
@moira@mastodon.murkworks.net avatar

@linux_mclinuxface I only use plant-sourced plastics, so PHA and PLA are of more interest to me. I've had some success using PLA outdoors. (My air quality sensor is sitting on a custom PLA mounting rack right now, in a relatively shaded area. It should be fine indefinitely.)

I might be willing to use PETG if I ever set up one of those 2-litre-bottle-to-thread recycling systems, though.

But mostly, I want my prints to get their carbon from the atmosphere (via plants), not from the ground.

linux_mclinuxface,
@linux_mclinuxface@fosstodon.org avatar

@moira that’s fair & respectable.

moira,
@moira@mastodon.murkworks.net avatar

I want to stress this is not temperature directly; these objects are reused from a glass point verification test, holds its shape to much higher temperatures than .

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